Competition between Covalent Bonding and Charge Transfer at Complex-Oxide Interfaces
نویسندگان
چکیده
منابع مشابه
Competition between covalent bonding and charge transfer at complex-oxide interfaces.
Here we study the electronic properties of cuprate-manganite interfaces. By means of atomic resolution electron microscopy and spectroscopy, we produce a subnanometer scale map of the transition metal oxidation state profile across the interface between the high Tc superconductor YBa2Cu3O7-δ and the colossal magnetoresistance compound (La,Ca)MnO3. A net transfer of electrons from manganite to c...
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Orbital reconstructions and covalent bonding must be considered as important factors in the rational design of oxide heterostructures with engineered physical properties. We have investigated the interface between high-temperature superconducting (Y,Ca)Ba(2)Cu3O7 and metallic La(0.67)Ca(0.33)MnO3 by resonant x-ray spectroscopy. A charge of about -0.2 electron is transferred from Mn to Cu ions a...
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ژورنال
عنوان ژورنال: Physical Review Letters
سال: 2014
ISSN: 0031-9007,1079-7114
DOI: 10.1103/physrevlett.112.196802